diff --git a/util/upf2qso/README b/util/upf2qso/README new file mode 100644 index 0000000..13ecd78 --- /dev/null +++ b/util/upf2qso/README @@ -0,0 +1,19 @@ + + upf2qso.C is a program that converts norm-conserving pseudopotentials + written in the UPF format (see http://www.pwscf.org) to the + www.quantum-simulation.org (QSO) format. + + upf2qso only works for norm-conserving potentials. Ultrasoft potentials + are not supported + + Test: + $ src/upf2qso 5.0 < data/C.pz-vbc.UPF > C.pz-vbc.xml + $ src/upf2qso 8.0 < data/Si.pz-vbc.UPF > Si.pz-vbc.xml + $ src/upf2qso 8.0 < data/30-Zn.LDA.fhi.UPF > Zn_FHI_LDA.xml + + Additional files v.dat, vlin.dat, upf.dat contain various functions in + gnuplot compatible format + + This program was written by F. Gygi + Debugging of version 1.2 was provided by Stefan Wippermann + Version 1.4, 2014-02-24. Fixed bug in 1.3 in calc of lmax diff --git a/util/upf2qso/data/30-Zn.LDA.fhi.UPF b/util/upf2qso/data/30-Zn.LDA.fhi.UPF new file mode 100644 index 0000000..6caffdf --- /dev/null +++ b/util/upf2qso/data/30-Zn.LDA.fhi.UPF @@ -0,0 +1,1215 @@ + +Generated using Fritz-Haber code +Author: unknown Generation date: as well +zinc, fhi98PP : Trouiller-Martins-type, LDA Ceperley/Alder Perdew/Wang (1992), local channel l=0 + 1 The Pseudo was generated with a Scalar-Relativistic Calculation +nl pn l occ Rcut Rcut US E pseu +4s 0 0 2.00 0.00000000000 0.00000000000 0.00000000000 +4p 0 1 0.00 0.00000000000 0.00000000000 0.00000000000 +3d 0 2 10.00 0.00000000000 0.00000000000 0.00000000000 + + + + + 0 Version Number + Zn Element + NC Norm - Conserving pseudopotential + F Nonlinear Core Correction +SLA PZ NOGX NOGC Exchange-Correlation functional + 12.00000000000 Z valence + 0.00000000000 Total energy + 0.00000 0.00000 Suggested cutoff for wfc and rho + 2 Max angular momentum component + 527 Number of 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b/util/upf2qso/data/Si.pz-vbc.UPF @@ -0,0 +1,895 @@ + +Generated using unknown code +Author: von Barth and Car Generation date: before 1984 +Info: Si LDA 3s2 3p2 VonBarth-Car, l=2 local + 0 The Pseudo was generated with a Non-Relativistic Calculation + 0.00000000000E+00 Local Potential cutoff radius +nl pn l occ Rcut Rcut US E pseu +3S 0 0 2.00 0.00000000000 0.00000000000 0.00000000000 +3P 0 1 2.00 0.00000000000 0.00000000000 0.00000000000 + + + + + 0 Version Number + Si Element + NC Norm - Conserving pseudopotential + F Nonlinear Core Correction + SLA PZ NOGX NOGC PZ Exchange-Correlation functional + 4.00000000000 Z valence + 0.00000000000 Total energy + 0.0000000 0.0000000 Suggested cutoff for wfc and rho + 1 Max angular momentum component + 431 Number of points in mesh + 2 2 Number of Wavefunctions, Number of Projectors + Wavefunctions nl l occ + 3S 0 2.00 + 3P 1 2.00 + + + + + + 1.30825992062E-03 1.34137867819E-03 1.37533584110E-03 1.41015263368E-03 + 1.44585081756E-03 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a/util/upf2qso/data/Si.pz-vbc.xml b/util/upf2qso/data/Si.pz-vbc.xml new file mode 100644 index 0000000..fa23f43 --- /dev/null +++ b/util/upf2qso/data/Si.pz-vbc.xml @@ -0,0 +1,4045 @@ + + + +Translated from UPF format by upf2qso +Generated using unknown code +Author: von Barth and Car Generation date: before 1984 +Info: Si LDA 3s2 3p2 VonBarth-Car, l=2 local + 0 The Pseudo was generated with a Non-Relativistic Calculation + 0.00000000000E+00 Local Potential cutoff radius +nl pn l occ Rcut Rcut US E pseu +3S 0 0 2.00 0.00000000000 0.00000000000 0.00000000000 +3P 0 1 2.00 0.00000000000 0.00000000000 0.00000000000 +SLA PZ NOGX NOGC + +Si +14 +28.0855 + +4 +2 +2 +0 +0.0 +0.01 + + +6.01180353958 +6.0098820204 +6.00401940924 +5.99425617775 +5.9806039917 +5.96307915256 +5.94170256804 +5.91649971301 +5.88750058278 +5.85473963778 +5.81825574012 +5.77809208256 +5.734296109 +5.68691942818 +5.63601771904 +5.58165063008 +5.52388167107 +5.46277809783 +5.39841079193 +5.33085413212 +5.26018586312 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+-0.500625773069 + + + + diff --git a/util/upf2qso/data/Zn_FHI_LDA.xml b/util/upf2qso/data/Zn_FHI_LDA.xml new file mode 100644 index 0000000..6b9189c --- /dev/null +++ b/util/upf2qso/data/Zn_FHI_LDA.xml @@ -0,0 +1,4847 @@ + + + +Translated from UPF format by upf2qso +Generated using Fritz-Haber code +Author: unknown Generation date: as well +zinc, fhi98PP : Trouiller-Martins-type, LDA Ceperley/Alder Perdew/Wang (1992), local channel l=0 + 1 The Pseudo was generated with a Scalar-Relativistic Calculation +nl pn l occ Rcut Rcut US E pseu +4s 0 0 2.00 0.00000000000 0.00000000000 0.00000000000 +4p 0 1 0.00 0.00000000000 0.00000000000 0.00000000000 +3d 0 2 10.00 0.00000000000 0.00000000000 0.00000000000 +SLA PZ NOGX NOGC + +Zn +30 +65.39 + +12 +2 +0 +0 +0.0 +0.01 + + +-9.8924907634 +-9.89247310144 +-9.89229861377 +-9.89162396116 +-9.88990017553 +-9.88644436716 +-9.88057417957 +-9.87178069378 +-9.85985917759 +-9.8449237067 +-9.82731321744 +-9.80746308969 +-9.78580676141 +-9.76272537426 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+0.000165489987244 +0.000163794897014 +0.000162117473137 +0.000160457535068 +0.000158814902261 +0.000157189394172 +0.000155580830255 + + + + diff --git a/util/upf2qso/src/Makefile b/util/upf2qso/src/Makefile new file mode 100644 index 0000000..7cdf2c0 --- /dev/null +++ b/util/upf2qso/src/Makefile @@ -0,0 +1,5 @@ +CXXFLAGS=-g +upf2qso: upf2qso.o PeriodicTable.o spline.o + $(CXX) -o $@ $^ +clean: + rm -f *.o upf2qso diff --git a/util/upf2qso/src/PeriodicTable.C b/util/upf2qso/src/PeriodicTable.C new file mode 100644 index 0000000..877bf6c --- /dev/null +++ b/util/upf2qso/src/PeriodicTable.C @@ -0,0 +1,175 @@ +//////////////////////////////////////////////////////////////////////////////// +// +// Copyright (c) 2009 The Regents of the University of California +// +// This file is part of Qbox +// +// Qbox is distributed under the terms of the GNU General Public License +// as published by the Free Software Foundation, either version 2 of +// the License, or (at your option) any later version. +// See the file COPYING in the root directory of this distribution +// or . +// +//////////////////////////////////////////////////////////////////////////////// +// +// PeriodicTable.C +// +//////////////////////////////////////////////////////////////////////////////// +// $Id: PeriodicTable.C,v 1.3 2009/02/14 22:47:30 fgygi Exp $ + +#include "PeriodicTable.h" +#include + +//////////////////////////////////////////////////////////////////////////////// +int PeriodicTable::z(string symbol) const +{ + map::const_iterator i = zmap.find(symbol); + assert( i != zmap.end() ); + return (*i).second; +} + +//////////////////////////////////////////////////////////////////////////////// +string PeriodicTable::symbol(int z) const +{ + assert(z>0 && z<=ptable.size()); + return ptable[z-1].symbol; +} + +//////////////////////////////////////////////////////////////////////////////// +string PeriodicTable::configuration(int z) const +{ + assert(z>0 && z<=ptable.size()); + return ptable[z-1].config; +} + +//////////////////////////////////////////////////////////////////////////////// +string PeriodicTable::configuration(string symbol) const +{ + return ptable[z(symbol)-1].config; +} + +//////////////////////////////////////////////////////////////////////////////// +double PeriodicTable::mass(int z) const +{ + assert(z>0 && z<=ptable.size()); + return ptable[z-1].mass; +} + +//////////////////////////////////////////////////////////////////////////////// +double PeriodicTable::mass(string symbol) const +{ + return ptable[z(symbol)-1].mass; +} + +//////////////////////////////////////////////////////////////////////////////// +int PeriodicTable::size(void) const +{ + return ptable.size(); +} + +//////////////////////////////////////////////////////////////////////////////// +PeriodicTable::PeriodicTable(void) +{ + ptable.push_back(Element(1,"H","1s1",1.00794)); + ptable.push_back(Element(2,"He","1s2",4.00260)); + ptable.push_back(Element(3, "Li","1s2 2s1", 6.941)); + ptable.push_back(Element(4, "Be","1s2 2s2", 9.01218)); + ptable.push_back(Element(5, "B", "1s2 2s2 2p1",10.811)); + ptable.push_back(Element(6, "C", "1s2 2s2 2p2",12.0107)); + ptable.push_back(Element(7, "N", "1s2 2s2 2p3",14.00674)); + ptable.push_back(Element(8, "O", "1s2 2s2 2p4",15.9994)); + ptable.push_back(Element(9, "F", "1s2 2s2 2p5",18.9884)); + ptable.push_back(Element(10,"Ne","1s2 2s2 2p6",20.1797)); + + ptable.push_back(Element(11,"Na","[Ne] 3s1", 22.98977)); + ptable.push_back(Element(12,"Mg","[Ne] 3s2", 24.3050)); + ptable.push_back(Element(13,"Al","[Ne] 3s2 3p1",26.98154)); + ptable.push_back(Element(14,"Si","[Ne] 3s2 3p2",28.0855)); + ptable.push_back(Element(15,"P", "[Ne] 3s2 3p3",30.97376)); + ptable.push_back(Element(16,"S", "[Ne] 3s2 3p4",32.066)); + ptable.push_back(Element(17,"Cl","[Ne] 3s2 3p5",35.4527)); + ptable.push_back(Element(18,"Ar","[Ne] 3s2 3p6",39.948)); + + ptable.push_back(Element(19,"K", "[Ar] 4s1",39.0983)); + ptable.push_back(Element(20,"Ca","[Ar] 4s2",40.078)); + ptable.push_back(Element(21,"Sc","[Ar] 3d1 4s2",44.95591)); + ptable.push_back(Element(22,"Ti","[Ar] 3d2 4s2",47.867)); + ptable.push_back(Element(23,"V", "[Ar] 3d3 4s2",50.9415)); + ptable.push_back(Element(24,"Cr","[Ar] 3d5 4s1",51.9961)); + ptable.push_back(Element(25,"Mn","[Ar] 3d5 4s2",54.93805)); + ptable.push_back(Element(26,"Fe","[Ar] 3d6 4s2",55.845)); + ptable.push_back(Element(27,"Co","[Ar] 3d7 4s2",58.9332)); + ptable.push_back(Element(28,"Ni","[Ar] 3d8 4s2",58.6934)); + ptable.push_back(Element(29,"Cu","[Ar] 3d10 4s1",63.546)); + ptable.push_back(Element(30,"Zn","[Ar] 3d10 4s2",65.39)); + ptable.push_back(Element(31,"Ga","[Ar] 3d10 4s2 4p1",69.723)); + ptable.push_back(Element(32,"Ge","[Ar] 3d10 4s2 4p2",72.61)); + ptable.push_back(Element(33,"As","[Ar] 3d10 4s2 4p3",74.9216)); + ptable.push_back(Element(34,"Se","[Ar] 3d10 4s2 4p4",78.96)); + ptable.push_back(Element(35,"Br","[Ar] 3d10 4s2 4p5",79.904)); + ptable.push_back(Element(36,"Kr","[Ar] 3d10 4s2 4p6",83.80)); + + ptable.push_back(Element(37,"Rb","[Kr] 5s1",85.4678)); + ptable.push_back(Element(38,"Sr","[Kr] 5s2",87.62)); + ptable.push_back(Element(39,"Y" ,"[Kr] 4d1 5s2",88.90585)); + ptable.push_back(Element(40,"Zr","[Kr] 4d2 5s2",91.224)); + ptable.push_back(Element(41,"Nb","[Kr] 4d4 5s1",92.90638)); + ptable.push_back(Element(42,"Mo","[Kr] 4d5 5s1",95.94)); + ptable.push_back(Element(43,"Tc","[Kr] 4d5 5s2",98.0)); + ptable.push_back(Element(44,"Ru","[Kr] 4d7 5s1",101.07)); + ptable.push_back(Element(45,"Rh","[Kr] 4d8 5s1",102.9055)); + ptable.push_back(Element(46,"Pd","[Kr] 4d10",106.42)); + ptable.push_back(Element(47,"Ag","[Kr] 4d10 5s1",107.8682)); + ptable.push_back(Element(48,"Cd","[Kr] 4d10 5s2",112.411)); + ptable.push_back(Element(49,"In","[Kr] 4d10 5s2 5p1",114.818)); + ptable.push_back(Element(50,"Sn","[Kr] 4d10 5s2 5p2",118.710)); + ptable.push_back(Element(51,"Sb","[Kr] 4d10 5s2 5p3",121.760)); + ptable.push_back(Element(52,"Te","[Kr] 4d10 5s2 5p4",127.60)); + ptable.push_back(Element(53,"I" ,"[Kr] 4d10 5s2 5p5",126.90447)); + ptable.push_back(Element(54,"Xe","[Kr] 4d10 5s2 5p6",131.29)); + + ptable.push_back(Element(55,"Cs","[Xe] 6s1",132.90545)); + ptable.push_back(Element(56,"Ba","[Xe] 6s2",137.327)); + ptable.push_back(Element(57,"La","[Xe] 5d1 6s2",138.9055)); + ptable.push_back(Element(58,"Ce","[Xe] 4f1 5d1 6s2",140.116)); + ptable.push_back(Element(59,"Pr","[Xe] 4f3 6s2",140.90765)); + ptable.push_back(Element(60,"Nd","[Xe] 4f4 6s2",144.24)); + ptable.push_back(Element(61,"Pm","[Xe] 4f5 6s2",145.0)); + ptable.push_back(Element(62,"Sm","[Xe] 4f6 6s2",150.36)); + ptable.push_back(Element(63,"Eu","[Xe] 4f7 6s2",151.964)); + ptable.push_back(Element(64,"Gd","[Xe] 4f7 5d1 6s2",157.25)); + ptable.push_back(Element(65,"Tb","[Xe] 4f9 6s2",158.92534)); + ptable.push_back(Element(66,"Dy","[Xe] 4f10 6s2",162.50)); + ptable.push_back(Element(67,"Ho","[Xe] 4f11 6s2",164.93032)); + ptable.push_back(Element(68,"Er","[Xe] 4f12 6s2",167.26)); + ptable.push_back(Element(69,"Tm","[Xe] 4f13 6s2",168.93421)); + ptable.push_back(Element(70,"Yb","[Xe] 4f14 6s2",173.04)); + ptable.push_back(Element(71,"Lu","[Xe] 4f14 5d1 6s2",174.967)); + ptable.push_back(Element(72,"Hf","[Xe] 4f14 5d2 6s2",178.49)); + ptable.push_back(Element(73,"Ta","[Xe] 4f14 5d3 6s2",180.9479)); + ptable.push_back(Element(74,"W" ,"[Xe] 4f14 5d4 6s2",183.84)); + ptable.push_back(Element(75,"Re","[Xe] 4f14 5d5 6s2",186.207)); + ptable.push_back(Element(76,"Os","[Xe] 4f14 5d6 6s2",190.23)); + ptable.push_back(Element(77,"Ir","[Xe] 4f14 5d7 6s2",192.217)); + ptable.push_back(Element(78,"Pt","[Xe] 4f14 5d9 6s1",195.078)); + ptable.push_back(Element(79,"Au","[Xe] 4f14 5d10 6s1",196.96655)); + ptable.push_back(Element(80,"Hg","[Xe] 4f14 5d10 6s2",200.59)); + ptable.push_back(Element(81,"Tl","[Xe] 4f14 5d10 6s2 6p1",204.3833)); + ptable.push_back(Element(82,"Pb","[Xe] 4f14 5d10 6s2 6p2",207.2)); + ptable.push_back(Element(83,"Bi","[Xe] 4f14 5d10 6s2 6p3",208.98038)); + ptable.push_back(Element(84,"Po","[Xe] 4f14 5d10 6s2 6p4",209.0)); + ptable.push_back(Element(85,"At","[Xe] 4f14 5d10 6s2 6p5",210.0)); + ptable.push_back(Element(86,"Rn","[Xe] 4f14 5d10 6s2 6p6",222.0)); + + ptable.push_back(Element(87,"Fr","[Rn] 7s1",223.0)); + ptable.push_back(Element(88,"Ra","[Rn] 7s2",226.0)); + ptable.push_back(Element(89,"Ac","[Rn] 6d1 7s2",227.0)); + ptable.push_back(Element(90,"Th","[Rn] 6d2 7s2",232.0381)); + ptable.push_back(Element(91,"Pa","[Rn] 5f2 6d1 7s2",231.03588)); + ptable.push_back(Element(92,"U" ,"[Rn] 5f3 6d1 7s2",238.0289)); + ptable.push_back(Element(93,"Np","[Rn] 5f4 6d1 7s2",237.0)); + ptable.push_back(Element(94,"Pu","[Rn] 5f5 6d1 7s2",244.0)); + + for ( int i = 0; i < ptable.size(); i++ ) + zmap[ptable[i].symbol] = i+1; +} diff --git a/util/upf2qso/src/PeriodicTable.h b/util/upf2qso/src/PeriodicTable.h new file mode 100644 index 0000000..df7b0cd --- /dev/null +++ b/util/upf2qso/src/PeriodicTable.h @@ -0,0 +1,57 @@ +//////////////////////////////////////////////////////////////////////////////// +// +// Copyright (c) 2009 The Regents of the University of California +// +// This file is part of Qbox +// +// Qbox is distributed under the terms of the GNU General Public License +// as published by the Free Software Foundation, either version 2 of +// the License, or (at your option) any later version. +// See the file COPYING in the root directory of this distribution +// or . +// +//////////////////////////////////////////////////////////////////////////////// +// +// PeriodicTable.h +// +//////////////////////////////////////////////////////////////////////////////// +// $Id: PeriodicTable.h,v 1.2 2009/02/14 22:47:30 fgygi Exp $ + +#ifndef PERIODICTABLE_H +#define PERIODICTABLE_H + +#include +#include +#include +using namespace std; + +struct Element +{ + int z; + string symbol; + string config; + double mass; + Element(int zz, string s, string c, double m) : z(zz), symbol(s), config(c), + mass(m) {} +}; + +class PeriodicTable +{ + private: + + vector ptable; + map zmap; + + public: + + PeriodicTable(void); + int z(string symbol) const; + string symbol(int zval) const; + string configuration(int zval) const; + string configuration(string symbol) const; + double mass(int zval) const; + double mass(string symbol) const; + int size(void) const; + +}; +#endif diff --git a/util/upf2qso/src/spline.C b/util/upf2qso/src/spline.C new file mode 100644 index 0000000..361bbde --- /dev/null +++ b/util/upf2qso/src/spline.C @@ -0,0 +1,169 @@ +//////////////////////////////////////////////////////////////////////////////// +// +// Copyright (c) 2008 The Regents of the University of California +// +// This file is part of Qbox +// +// Qbox is distributed under the terms of the GNU General Public License +// as published by the Free Software Foundation, either version 2 of +// the License, or (at your option) any later version. +// See the file COPYING in the root directory of this distribution +// or . +// +/////////////////////////////////////////////////////////////////////////////// +// +// spline.C +// +/////////////////////////////////////////////////////////////////////////////// +// $Id: spline.C,v 1.5 2008/09/08 15:56:20 fgygi Exp $ +#include "spline.h" +#include + +void tridsolve(int n, double* d, double* e, double* f, double* x) +{ + // solve the tridiagonal system Ax=b + // d[i] = a(i,i) + // e[i] = a(i,i+1) (superdiagonal of A, e[n-1] not defined) + // f[i] = a(i,i-1) (subdiagonal of A, f[0] not defined) + // x[i] = right-hand side b as input + // x[i] = solution as output + + for ( int i = 1; i < n; i++ ) + { + f[i] /= d[i-1]; + d[i] -= f[i]*e[i-1]; + } + + for ( int i = 1; i < n; i++ ) + x[i] -= f[i]*x[i-1]; + + x[n-1] /= d[n-1]; + + for ( int i = n-2; i >= 0; i-- ) + x[i] = (x[i]-e[i]*x[i+1])/d[i]; +} + +void spline(int n, double *x, double *y, double yp_left, double yp_right, + int bcnat_left, int bcnat_right, double *y2) +{ + const double third = 1.0/3.0; + const double sixth = 1.0/6.0; + double *d = new double[n]; + double *e = new double[n]; + double *f = new double[n]; + if ( bcnat_left == 0 ) + { + // use derivative yp_left at x[0] + const double h = x[1]-x[0]; + assert(h>0.0); + d[0] = third*h; + e[0] = sixth*h; + f[0] = 0.0; + y2[0] = (y[1]-y[0])/h - yp_left; + } + else + { + // use natural spline at x[0] + d[0] = 1.0; + e[0] = 0.0; + f[0] = 0.0; + y2[0] = 0.0; + } + if ( bcnat_right == 0 ) + { + // use derivative yp_right at x[n-1] + const double h = x[n-1]-x[n-2]; + assert(h>0.0); + d[n-1] = third*h; + e[n-1] = 0.0; + f[n-1] = sixth*h; + y2[n-1] = yp_right - (y[n-1]-y[n-2])/h; + } + else + { + // use natural spline at x[n-1] + d[n-1] = 1.0; + e[n-1] = 0.0; + f[n-1] = 0.0; + y2[n-1] = 0.0; + } + + // tridiagonal matrix + for ( int i = 1; i < n-1; i++ ) + { + const double hp = x[i+1]-x[i]; + const double hm = x[i]-x[i-1]; + assert(hp>0.0); + assert(hm>0.0); + d[i] = third * (hp+hm); + e[i] = sixth * hp; + f[i] = sixth * hm; + y2[i] = (y[i+1]-y[i])/hp - (y[i]-y[i-1])/hm; + } + + tridsolve(n,d,e,f,y2); + + delete [] d; + delete [] e; + delete [] f; +} + +void splint (int n, double *xa, double *ya, double *y2a, double x, double *y) +{ + int k; + double a,b,h; + + int kl = 0; + int kh = n-1; + + while ( kh - kl > 1 ) + { + k = ( kh + kl ) / 2; + if ( xa[k] > x ) + kh = k; + else + kl = k; + } + + h = xa[kh] - xa[kl]; + assert ( h > 0.0 ); + + a = ( xa[kh] - x ) / h; + b = ( x - xa[kl] ) / h; + + *y = a * ya[kl] + b * ya[kh] + h * h * (1.0/6.0) * + ( (a*a*a-a) * y2a[kl] + (b*b*b-b) * y2a[kh] ); + +} + +void splintd (int n, double *xa, double *ya, double *y2a, + double x, double *y, double *dy) +{ + int k; + double a,b,h; + + int kl = 0; + int kh = n-1; + + while ( kh - kl > 1 ) + { + k = ( kh + kl ) / 2; + if ( xa[k] > x ) + kh = k; + else + kl = k; + } + + h = xa[kh] - xa[kl]; + assert ( h > 0.0 ); + + a = ( xa[kh] - x ) / h; + b = ( x - xa[kl] ) / h; + + *y = a * ya[kl] + b * ya[kh] + h * h * (1.0/6.0) * + ( (a*a*a-a) * y2a[kl] + (b*b*b-b) * y2a[kh] ); + + *dy = ( ya[kh] - ya[kl] ) / h + + h * ( ( (1.0/6.0) - 0.5 * a * a ) * y2a[kl] + + ( 0.5 * b * b - (1.0/6.0) ) * y2a[kh] ); +} diff --git a/util/upf2qso/src/spline.h b/util/upf2qso/src/spline.h new file mode 100644 index 0000000..908c317 --- /dev/null +++ b/util/upf2qso/src/spline.h @@ -0,0 +1,23 @@ +//////////////////////////////////////////////////////////////////////////////// +// +// Copyright (c) 2008 The Regents of the University of California +// +// This file is part of Qbox +// +// Qbox is distributed under the terms of the GNU General Public License +// as published by the Free Software Foundation, either version 2 of +// the License, or (at your option) any later version. +// See the file COPYING in the root directory of this distribution +// or . +// +/////////////////////////////////////////////////////////////////////////////// +// +// spline.h +// +/////////////////////////////////////////////////////////////////////////////// +// $Id: spline.h,v 1.5 2008/09/08 15:56:20 fgygi Exp $ +void spline(int n, double *x, double *y, double yp_left, double yp_right, + int bcnat_left, int bcnat_right, double *y2); +void splint (int n, double *xa, double *ya, double *y2a, double x, double *y); +void splintd (int n, double *xa, double *ya, double *y2a, + double x, double *y, double *dy); diff --git a/util/upf2qso/src/upf2qso.C b/util/upf2qso/src/upf2qso.C new file mode 100644 index 0000000..ed99915 --- /dev/null +++ b/util/upf2qso/src/upf2qso.C @@ -0,0 +1,646 @@ +//////////////////////////////////////////////////////////////////////////////// +// +// Copyright (c) 2009 The Regents of the University of California +// +// This file is part of Qbox +// +// Qbox is distributed under the terms of the GNU General Public License +// as published by the Free Software Foundation, either version 2 of +// the License, or (at your option) any later version. +// See the file COPYING in the root directory of this distribution +// or . +// +//////////////////////////////////////////////////////////////////////////////// +// +// upf2qso.C: transform a UPF pseudopotential to QSO format +// the QSO format is defined at http://www.quantum-simulation.org +// +//////////////////////////////////////////////////////////////////////////////// +// +// use: upf2qso rcut(a.u.) < pot.UPF > pot.xml +// The potentials in pot.xml are given on a radial linear grid up to rcut, +// with grid spacing of 0.01 (a.u.) +// +#include +#include +#include +#include +#include +#include +#include +#include +#include +#include "spline.h" +#include "PeriodicTable.h" +using namespace std; + +int seek_tag(string tag) +{ + // skip to line following tag + bool done = false; + string buf, s; + istringstream is; + + while ( !done ) + { + getline(cin,buf); + is.clear(); + is.str(buf); + is >> s; + done = ( s == tag ); + if ( cin.eof() ) + { + cerr << " found EOF before " << tag << endl; + return 1; + } + } + return 0; +} + +int main(int argc, char** argv) +{ + cerr << " upf2qso v1.4 2014-02-24" << endl; + if ( argc != 2 ) + { + cerr << " usage: upf2qso rcut < file.upf > file.xml" << endl; + return 1; + } + assert(argc==2); + const double rcut = atof(argv[1]); + + PeriodicTable pt; + string buf,s; + istringstream is; + int status; + + string upf_pp_info; + status = seek_tag(""); + bool done = false; + while (!done) + { + getline(cin,buf); + is.clear(); + is.str(buf); + is >> s; + done = ( s == "" ); + if ( !done ) + { + upf_pp_info += buf + '\n'; + } + } + + // remove all '<' and '>' characters from the PP_INFO field + // for XML compatibility + string::size_type p = upf_pp_info.find_first_of("<>"); + while ( p != string::npos ) + { + upf_pp_info[p] = ' '; + p = upf_pp_info.find_first_of("<>"); + } + + status = seek_tag(""); + + // version number (ignore) + getline(cin,buf); + + // element symbol + string upf_symbol; + getline(cin,buf); + is.clear(); + is.str(buf); + is >> upf_symbol; + + // get atomic number and mass + const int atomic_number = pt.z(upf_symbol); + const double mass = pt.mass(upf_symbol); + + // NC flag + string upf_ncflag; + getline(cin,buf); + is.clear(); + is.str(buf); + is >> upf_ncflag; + if ( upf_ncflag != "NC" ) + { + cerr << " not a Norm-conserving potential" << endl; + cerr << " NC flag: " << upf_ncflag << endl; + return 1; + } + + // NLCC flag + string upf_nlcc_flag; + getline(cin,buf); + is.clear(); + is.str(buf); + is >> upf_nlcc_flag; + if ( upf_nlcc_flag != "F" ) + { + cerr << " Potential includes a non-linear core correction" << endl; + return 1; + } + + // XC functional (add in description) + string upf_xcf[4]; + getline(cin,buf); + is.clear(); + is.str(buf); + is >> upf_xcf[0] >> upf_xcf[1] >> upf_xcf[2] >> upf_xcf[3]; + + // add XC functional information to description + upf_pp_info += upf_xcf[0] + ' ' + upf_xcf[1] + ' ' + + upf_xcf[2] + ' ' + upf_xcf[3] + '\n'; + + // Z valence + double upf_zval; + getline(cin,buf); + is.clear(); + is.str(buf); + is >> upf_zval; + + // Total energy (ignore) + getline(cin,buf); + + // suggested cutoff (ignore) + getline(cin,buf); + + // max angular momentum + int upf_lmax; + getline(cin,buf); + is.clear(); + is.str(buf); + is >> upf_lmax; + + // number of points in mesh + int upf_mesh_size; + getline(cin,buf); + is.clear(); + is.str(buf); + is >> upf_mesh_size; + + // number of wavefunctions, number of projectors + int upf_nwf, upf_nproj; + getline(cin,buf); + is.clear(); + is.str(buf); + is >> upf_nwf >> upf_nproj; + + // Wavefunctions + vector upf_shell(upf_nwf); + vector upf_l(upf_nwf); + vector upf_occ(upf_nwf); + // skip header + getline(cin,buf); + for ( int ip = 0; ip < upf_nwf; ip++ ) + { + getline(cin,buf); + is.clear(); + is.str(buf); + is >> upf_shell[ip] >> upf_l[ip] >> upf_occ[ip]; + } + status = seek_tag(""); + if ( status != 0 ) return status; + + // read mesh + status = seek_tag(""); + if ( status != 0 ) return status; + status = seek_tag(""); + if ( status != 0 ) return status; + vector upf_r(upf_mesh_size); + for ( int i = 0; i < upf_mesh_size; i++ ) + cin >> upf_r[i]; + status = seek_tag(""); + if ( status != 0 ) return status; + status = seek_tag(""); + if ( status != 0 ) return status; + vector upf_rab(upf_mesh_size); + for ( int i = 0; i < upf_mesh_size; i++ ) + cin >> upf_rab[i]; + status = seek_tag(""); + if ( status != 0 ) return status; + status = seek_tag(""); + if ( status != 0 ) return status; + + status = seek_tag(""); + if ( status != 0 ) return status; + vector upf_vloc(upf_mesh_size); + for ( int i = 0; i < upf_mesh_size; i++ ) + cin >> upf_vloc[i]; + status = seek_tag(""); + if ( status != 0 ) return status; + + status = seek_tag(""); + if ( status != 0 ) return status; + vector > upf_vnl; + upf_vnl.resize(upf_nproj); + vector upf_proj_l(upf_nproj); + for ( int j = 0; j < upf_nproj; j++ ) + { + status = seek_tag(""); + if ( status != 0 ) return status; + int ip, l, np; + cin >> ip >> l; + while ( cin.get() != '\n' ); + assert(ip-1 < upf_nproj); + assert(l <= upf_lmax); + upf_proj_l[ip-1] = l; + cin >> np; + upf_vnl[j].resize(upf_mesh_size); + for ( int i = 0; i < np; i++ ) + cin >> upf_vnl[j][i]; + status = seek_tag(""); + if ( status != 0 ) return status; + } + status = seek_tag(""); + if ( status != 0 ) return status; + int upf_ndij; + cin >> upf_ndij; + while ( cin.get() != '\n' ); + if ( upf_ndij != upf_nproj ) + { + cerr << " Number of non-zero Dij differs from number of projectors" << endl; + return 1; + } + + vector upf_d(upf_ndij); + for ( int i = 0; i < upf_ndij; i++ ) + { + int m,n; + cin >> m >> n >> upf_d[i]; + if ( m != n ) + { + cerr << " Non-local Dij has off-diagonal elements" << endl; + cerr << " m=" << m << " n=" << n << endl; + return 1; + } + } + status = seek_tag(""); + if ( status != 0 ) return status; + + status = seek_tag(""); + if ( status != 0 ) return status; + + // make table iproj[l] mapping l to iproj + // vnl(l) is in vnl[iproj[l]] if iproj[l] > -1 + // vlocal if iproj[llocal] = -1 + vector iproj(upf_lmax+2); + for ( int l = 0; l <= upf_lmax+1; l++ ) + iproj[l] = -1; + for ( int j = 0; j < upf_nproj; j++ ) + iproj[upf_proj_l[j]] = j; + + // determine angular momentum of local potential in UPF file + int upf_llocal; + // reverse loop to get correct upf_llocal when upf_nproj < upf_lmax + for ( int l = upf_lmax+1; l >= 0; l-- ) + if ( iproj[l] == -1 ) + upf_llocal = l; + // increase lmax if there are more projectors than wavefunctions + int qso_lmax = upf_lmax; + if (upf_lmax < upf_llocal) + { + qso_lmax = upf_lmax+1; + } + + status = seek_tag(""); + vector > upf_wf; + vector upf_wf_l(upf_nwf); + vector upf_wf_occ(upf_nwf); + upf_wf.resize(upf_nwf); + for ( int j = 0; j < upf_nwf; j++ ) + { + upf_wf[j].resize(upf_mesh_size); + string label; + cin >> label >> upf_wf_l[j] >> upf_wf_occ[j]; + while ( cin.get() != '\n' ); + for ( int i = 0; i < upf_mesh_size; i++ ) + cin >> upf_wf[j][i]; + } + status = seek_tag(""); + if ( status != 0 ) return status; + + // output original data in file upf.dat + ofstream upf("upf.dat"); + upf << "# vloc" << endl; + for ( int i = 0; i < upf_vloc.size(); i++ ) + upf << upf_r[i] << " " << upf_vloc[i] << endl; + upf << endl << endl; + for ( int j = 0; j < upf_nproj; j++ ) + { + upf << "# proj j=" << j << endl; + for ( int i = 0; i < upf_vnl[j].size(); i++ ) + upf << upf_r[i] << " " << upf_vnl[j][i] << endl; + upf << endl << endl; + } + for ( int j = 0; j < upf_nwf; j++ ) + { + upf << "# wf j=" << j << endl; + for ( int i = 0; i < upf_wf[j].size(); i++ ) + upf << upf_r[i] << " " << upf_wf[j][i] << endl; + upf << endl << endl; + } + upf.close(); + + + // print summary + cerr << "PP_INFO:" << endl << upf_pp_info << endl; + cerr << "Element: " << upf_symbol << endl; + cerr << "NC: " << upf_ncflag << endl; + cerr << "NLCC: " << upf_nlcc_flag << endl; + cerr << "XC: " << upf_xcf[0] << " " << upf_xcf[1] << " " + << upf_xcf[2] << " " << upf_xcf[3] << endl; + cerr << "Zv: " << upf_zval << endl; + cerr << "lmax: " << qso_lmax << endl; + cerr << "llocal: " << upf_llocal << endl; + cerr << "nwf: " << upf_nwf << endl; + cerr << "mesh_size: " << upf_mesh_size << endl; + + // interpolate functions on linear mesh + + // compute delta_vnl[l][i] on the upf log mesh + + // divide the projector function by the wavefunction, except if + // the wavefunction amplitude is smaller than tol, outside of rcut_divide. + const double tol = 1.e-5; + const double rcut_divide = 1.0; + vector > delta_vnl; + delta_vnl.resize(upf_nproj); + for ( int j = 0; j < upf_nproj; j++ ) + { + delta_vnl[j].resize(upf_wf[j].size()); + for ( int i = 0; i < delta_vnl[j].size(); i++ ) + { + double num = upf_vnl[j][i]; + double den = upf_wf[upf_proj_l[j]][i]; + + delta_vnl[j][i] = 0.0; + if ( upf_r[i] < rcut_divide ) + { + // near the origin + if ( i == 0 && fabs(den) < tol ) + { + // i = 0 for linear mesh, r = 0.0: use nearest value + delta_vnl[j][i] = upf_vnl[j][1] / upf_wf[upf_proj_l[j]][1]; + } + else + { + // other points near the origin + delta_vnl[j][i] = num / den; + } + } + else + { + // wavefunction gets small at large r. + // Assume that delta_vnl is zero when that happens + if ( fabs(den) > tol ) + delta_vnl[j][i] = num / den; + } + } + } + + vector > vps; + vps.resize(upf_nproj+1); + for ( int j = 0; j < upf_nproj; j++ ) + { + vps[j].resize(upf_mesh_size); + for ( int i = 0; i < delta_vnl[j].size(); i++ ) + vps[j][i] = upf_vloc[i] + delta_vnl[j][i]; + } + + // interpolate vloc + vector f(upf_mesh_size), fspl(upf_mesh_size); + + // factor 0.5: convert from Ry in UPF to Hartree in QSO + for ( int i = 0; i < upf_vloc.size(); i++ ) + f[i] = 0.5 * upf_vloc[i]; + + int n = upf_vloc.size(); + int bcnat_left = 0; + double yp_left = 0.0; + int bcnat_right = 1; + double yp_right = 0.0; + spline(n,&upf_r[0],&f[0],yp_left,yp_right, + bcnat_left,bcnat_right,&fspl[0]); + + const double mesh_spacing = 0.01; + int nplin = (int) (rcut / mesh_spacing); + + vector vloc_lin(nplin); + for ( int i = 0; i < nplin; i++ ) + { + double r = i * mesh_spacing; + if ( r >= upf_r[0] ) + splint(n,&upf_r[0],&f[0],&fspl[0],r,&vloc_lin[i]); + else + // use value closest to the origin for r=0 + vloc_lin[i] = 0.5 * upf_vloc[0]; + } + + // interpolate vps[j], j=0, nproj-1 + vector > vps_lin; + vps_lin.resize(vps.size()); + for ( int j = 0; j < vps.size(); j++ ) + { + vps_lin[j].resize(nplin); + } + + for ( int j = 0; j < upf_nproj; j++ ) + { + // factor 0.5: convert from Ry in UPF to Hartree in QSO + for ( int i = 0; i < upf_vloc.size(); i++ ) + f[i] = 0.5 * vps[j][i]; + + int n = upf_vloc.size(); + int bcnat_left = 0; + double yp_left = 0.0; + int bcnat_right = 1; + double yp_right = 0.0; + spline(n,&upf_r[0],&f[0],yp_left,yp_right, + bcnat_left,bcnat_right,&fspl[0]); + + for ( int i = 0; i < nplin; i++ ) + { + double r = i * mesh_spacing; + if ( r >= upf_r[0] ) + splint(n,&upf_r[0],&f[0],&fspl[0],r,&vps_lin[j][i]); + else + vps_lin[j][i] = 0.5 * vps[j][0]; + } + } + + // write potentials in gnuplot format on file vlin.dat + ofstream vlin("vlin.dat"); + for ( int l = 0; l <= qso_lmax; l++ ) + { + vlin << "# v, l=" << l << endl; + if ( iproj[l] == -1 ) + { + // l == llocal + for ( int i = 0; i < nplin; i++ ) + vlin << i*mesh_spacing << " " << vloc_lin[i] << endl; + vlin << endl << endl; + } + else + { + for ( int i = 0; i < nplin; i++ ) + vlin << i*mesh_spacing << " " << vps_lin[iproj[l]][i] << endl; + vlin << endl << endl; + } + } + + // interpolate wavefunctions on the linear mesh + + vector > wf_lin; + wf_lin.resize(upf_nwf); + for ( int j = 0; j < upf_nwf; j++ ) + { + wf_lin[j].resize(nplin); + assert(upf_wf[j].size()<=f.size()); + for ( int i = 0; i < upf_wf[j].size(); i++ ) + { + if ( upf_r[i] > 0.0 ) + f[i] = upf_wf[j][i] / upf_r[i]; + else + { + // value at origin, depending on angular momentum + if ( upf_wf_l[j] == 0 ) + { + // l=0: take value closest to r=0 + f[i] = upf_wf[j][1]/upf_r[1]; + } + else + { + // l>0: + f[i] = 0.0; + } + } + } + + int n = upf_wf[j].size(); + // choose boundary condition at origin depending on angular momentum + int bcnat_left = 0; + double yp_left = 0.0; + if ( upf_wf_l[j] == 1 ) + { + bcnat_left = 1; // use natural bc + double yp_left = 0.0; // not used + } + int bcnat_right = 1; + double yp_right = 0.0; + spline(n,&upf_r[0],&f[0],yp_left,yp_right, + bcnat_left,bcnat_right,&fspl[0]); + + for ( int i = 0; i < nplin; i++ ) + { + double r = i * mesh_spacing; + if ( r >= upf_r[0] ) + splint(n,&upf_r[0],&f[0],&fspl[0],r,&wf_lin[j][i]); + else + { + // r < upf_r[0] + assert(upf_r[0]>0.0); + // compute value near origin, depending on angular momentum + if ( upf_wf_l[j] == 0 ) + { + // l=0: take value closest to r=0 + wf_lin[j][i] = upf_wf[j][0]/upf_r[0]; + } + else + { + // l>0: + wf_lin[j][i] = upf_wf[j][0] * r / ( upf_r[0] * upf_r[0] ); + } + } + } + + vlin << "# phi, l=" << upf_l[j] << endl; + for ( int i = 0; i < nplin; i++ ) + vlin << i*mesh_spacing << " " << wf_lin[j][i] << endl; + vlin << endl << endl; + } + + cerr << " interpolation done" << endl; + +#if 1 + // output potential on log mesh + ofstream vout("v.dat"); + for ( int l = 0; l <= qso_lmax; l++ ) + { + vout << "# v, l=" << l << endl; + if ( iproj[l] == -1 ) + { + // l == llocal + for ( int i = 0; i < upf_vloc.size(); i++ ) + vout << upf_r[i] << " " << 0.5*upf_vloc[i] << endl; + vout << endl << endl; + } + else + { + for ( int i = 0; i < vps[iproj[l]].size(); i++ ) + vout << upf_r[i] << " " << 0.5*vps[iproj[l]][i] << endl; + vout << endl << endl; + } + } + vout << endl << endl; + vout.close(); +#endif + + // Generate QSO file + + // output potential in QSO format + cout << "" << endl; + cout << "" << endl; + cout << "" << endl; + cout << "Translated from UPF format by upf2qso" << endl; + cout << upf_pp_info; + cout << "" << endl; + cout << "" << upf_symbol << "" << endl; + cout << "" << atomic_number << "" << endl; + cout << "" << mass << "" << endl; + cout << "" << endl; + cout << "" << upf_zval << "" << endl; + cout << "" << qso_lmax << "" << endl; + cout << "" << upf_llocal << "" << endl; + cout << "0" << endl; + cout << "0.0" << endl; + cout << "" << mesh_spacing << "" << endl; + + for ( int l = 0; l <= qso_lmax; l++ ) + { + cout << "" + << endl; + cout << "" << endl; + if ( iproj[l] == -1 ) + { + // l == llocal + for ( int i = 0; i < nplin; i++ ) + cout << setprecision(12) << vloc_lin[i] << endl; + } + else + { + for ( int i = 0; i < nplin; i++ ) + cout << setprecision(12) << vps_lin[iproj[l]][i] << endl; + } + cout << "" << endl; + // find index j corresponding to angular momentum l + int j = 0; + while ( upf_wf_l[j] != l && j < upf_nwf ) j++; + // check if found + const bool found = ( j != upf_nwf ); + // print wf only if found + if ( found ) + { + cout << "" << endl; + for ( int i = 0; i < nplin; i++ ) + cout << setprecision(12) << wf_lin[j][i] << endl; + cout << "" << endl; + } + cout << "" << endl; + } + cout << "" << endl; + cout << "" << endl; + return 0; +} +